Viscosity is a measure of the resistance of a fluid to deformation under shear stress. It is commonly perceived as "thickness", or resistance to pouring. Viscosity describes a fluid's internal resistance to flow and may be thought of as a measure of fluid friction. Thus, methanol is "thin"; having a low viscosity, while vegetable oil is "thick" having a high viscosity.
When a shear stress is applied to a solid body, the body deforms until the deformation results in an opposing force to balance that applied, an equilibrium. However, when a shear stress is applied to a fluid, such as a wind blowing over the surface of the ocean, the fluid flows, and continues to flow while the stress is applied. When the stress is removed, in general, the flow decays due to internal dissipation of energy. The "thicker" the fluid, the greater its resistance to shear stress and the more rapid the decay of its flow.
In general, in any flow, layers move at different velocities and the fluid's "thickness" arises from the shear stress between the layers that ultimately oppose any applied force.
Isaac Newton postulated that, for straight, parallel and uniform flow, the shear stress, τ, between layers is proportional to the velocity gradient, ∂u/∂y, in the direction perpendicular to the layers, in other words, the relative motion of the layers.
Here, the constant μ is known as the coefficient of viscosity, viscosity, or dynamic viscosity. Many fluids, such as water and most gases satisfy Newton's criterion and are known as Newtonian fluids. Non-Newtonian fluids exhibit a more complicated relationship between shear stress and velocity gradient than simple linearity.
In many situations, we are concerned with the ratio of the viscous force to the inertial force, the latter characterised by the fluid density ρ. This ratio is characterised by the kinematic viscosity, defined as follows:
James Clerk Maxwell called viscosity fugitive elasticity because of the analogy that elastic deformation opposes shear stress in solids, while in viscous fluids; shear stress is opposed by rate of deformation.
Viscosity is the principal means by which energy is dissipated in fluid motion, typically as heat.
Measurement of viscosity
Viscosity is measured with various types of viscometer, typically at 25°C (standard state).
Viscosity (dynamic viscosity)
The SI physical unit of dynamic viscosity is the pascal-second (Pa•s), which is identical to 1 N•s/m2 or 1 kg/(m•s). In France there have been some attempts to establish the poiseuille (Pl) as a name for the Pa•s but without international success. Care must be taken in not confusing the poiseuille with the poise named after the same person!
The cgs physical unit for dynamic viscosity is the poise (P) named after Jean Louis Marie Poiseuille. It is more commonly expressed, particularly in ASTM standards, as centipoises (cP). The centipoises are commonly used because water has a viscosity of 1.0 cP (at 20 °C).
1 poise = 100 centipoises = 1 g/(cm•s) = 0.1 Pa•s.
The SI physical unit of kinematic viscosity is the (m2/s). The cgs physical unit for kinematic viscosity is the stokes (abbreviated S or St), named after George Gabriel Stokes . It is sometimes expressed in terms of centistokes (cS or cSt). In U.S. usage, stoke is sometimes used as the singular form.
1 stokes = 100 centistokes = 1 cm2/s = 0.0001 m2/s.
The viscosity of a system is determined by how molecules comprising the system interact. There are no simple but correct expressions for the viscosity of a fluid. The simplest exact expressions are the Green-Kubo relations for the linear shear viscosity or the Transient Time Correlation Function expressions derived by Evans and Morris’s in 1985. Although these expressions are each exact in order to calculate the viscosity of a dense fluid, using these relations requires the use of molecular dynamics computer simulation.
Viscosity in gases arises principally from the molecular diffusion that transports momentum between layers of flow. The kinetic theory of gases allows accurate prediction of the behaviour of gaseous viscosity, in particular that, within the regime where the theory is applicable:
Viscosity is independent of pressure; and
Viscosity increases as temperature increases.
In liquids, the additional forces between molecules become important. This leads to an additional contribution to the shear stress though the exact mechanics of this are still controversial. Thus, in liquids:
Viscosity is independent of pressure (except at very high pressure); and
Viscosity tends to fall as temperature increases.
The dynamic viscosities of liquids are typically several orders of magnitude higher than dynamic viscosities of gases.
Viscosity of some common materials
Some dynamic viscosities of Newtonian fluids are listed below:
Gases (at 0 °C):
hydrogen 8.4 × 10-6
air 17.4 × 10-6
xenon 21.2 × 10-6
Liquids (at 20 °C):
ethyl alcohol 0.248 × 10-3
acetone 0.326 × 10-3
methanol 0.59 × 10-3
benzene 0.64 × 10-3
water 1.025 × 10-3
nitrobenzol 2.0 × 10-3
mercury 17.0 × 10-3
sulphuric acid 30 × 10-3
olive oil 81 × 10-3
castor oil 0.985
Many fluids such as honey have a wide range of viscosities.
Can solids have a viscosity?
It is commonly asserted that amorphous solids, such as glass, have viscosity, arguing on the basis that all solids flow, to some possibly minuscule extent, in response to shear stress. Advocates of such a view hold that the distinction between solids and liquids is unclear and that solids are simply liquids with a very high viscosity, typically greater than 1012 Pa•s. This position is often adopted by supporters of the widely held urban myth that glass flow can be observed in old buildings.
However, others argue that solids are, in general, elastic for small stresses while fluids are not. Even if solids flow at higher stresses, they are characterized by their low-stress behaviour. Viscosity may be an appropriate characteristic for solids in a plastic regime. The situation becomes somewhat confused as the term viscosity is sometimes used for solid materials, for example Maxwell materials, to describe the relationship between stress and the rate of change of strain, rather than rate of shear.
These distinctions may be largely resolved by considering the constitutive equations of the material in question, which take into account both its viscous and elastic behaviours. Materials for which both their viscosity and their elasticity are important in a particular range of deformation and deformation rate are called viscoelastic.
One example of solids flowing which has been observed since 1930 is the Pitch drop experiment.
In the study of turbulence in fluids, a common practical strategy for calculation is to ignore the small-scale vortices (or eddies) in the motion and to calculate a large-scale motion with an eddy viscosity that characterizes the transport and dissipation of energy in the smaller-scale flow. Typical values of eddy viscosity used in modelling ocean circulation are in excess of 107 Pa•s.
The reciprocal of viscosity is fluidity, usually symbolised by φ (=1/μ), measured in reciprocal poise (cm•s/g), sometimes called the rhe. Fluidity is seldom used in engineering practice.
The word "viscosity" derives from the Latin word "viscum" for mistletoe. From the mistletoe berries a viscous glue has been made and used for lime-twigs to catch birds.